Yes, she does sing in the song "Sugarhigh" from the movie Empire Records.
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License to Drive, Empire Records, Hardware (video of them on TV)
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Nicole Kidman, Renee Zellweger, Eileen Atkins, Natalie Portman, Kathy Baker, to name a few
You can find a summary of the movie, Empire, at this link: http://www.celebritywonder.com/movie/2002_Empire.html
It is at the beginning of the movie "The Empire Strikes Back"