Yes. The name of the song is the rather longwinded 'It Overtakes Me/The Stars Are So Big, I Am So Small... Do I Stand A Chance?'
The song features on the band's 2006 studio album 'At War With The Mystics'.
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Apparently (from what a rep told me) it is some proprietary piece...I am looking for it as well...Let me know slim Is it the Carolina liar Show me what I'm looking for?
You might be thinking of The Polyphonic Spree, who performed "Light and Day" on episode 3.19: My Choosiest Choice of All.
It's The W.A.N.D. by the Flamming Lips The band is actually New Young Pony Club not Flaming Lips.
they are calledAvicii - Levelsis the song
Don't fear the reaper