At this point and time it hasn't
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Ash's Grovyle evolves into Sceptile in the Advanced Geneation series episode number 161 titled 'Odd Pokemon Out!'.
it evolves in reversing the charges,it is the 154th episode of the Advanced Generation series, and the 428th episode of the Pokémon anime. It was first broadcast in Japan on December 1, 2005 and in the United States on October 7, 2006.
yes Leonidas can
There is no specific level at which Riolu evolves. You must get it to like you. To do this give Riolu the soothe bell and have him first in your party. Enter him in competitions and have him win battles. He will like you more and more and will evolve in a short while. put him first in party, give him poffins and soothe bell win battles and he will usually evolve round lvl 30
By the process of natural selection and adaptation to a continuously changing environment.