No. Not yet, at least.
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for the second time it could possibly be naruto shippuden episode 217 as manga 475 is naruto shippuden episode 208 and in manga it is only 9 more chapters left until they meet again so it could be somewhere between naruto shippuden 215 and 219
Yes and No at the same time. Gaara has the Shukaku when he is a little boy. But when we get to the Shippuden episodes he soon loses his Shukaku and is brought back to life by Grandma Chiyo. Even though he doesn't have his Shukaku he is still able to be Kazekage and control sand. (i answered this question because i know almost everything about Gaara. I'm not obsessed but i love him ALOT!) ^ ^ ^to add a little bit more for those of you who are wondering. Shukaku did NOT give Gaara the power to control sand. That is a common misconception. Shukaku gave Gaara "ultimate protection". Basically Shukaku amplified Gaara's sand by controlling it himself, thus allowing the sand to protect Gaara even when Gaara did not wish it. Gaara's ninjutsu though is the ability to control sand. Now that Shukaku is gone though, Gaara has to use ninja signs in order to control his jutsu, instead of relying on Shukaku to kick butt for him xD Non-the-less Gaara is still my second favourite character. The only person i like more that Gaara is Hidan xD ^ ^ ^ haha hidan. he's kinda lame. he's so emo. XD gaara's favorite. then kakashi. so yeah gaara still has his sand powers but now he can 'feel pain'. because before the shukaku wouldn't let him get hurt.
episode 90 called "A Shinobi's Determination"
He is an antagonist from when he shows up in Konoha for the chuunin exams until he is defeated by Naruto and has his mind changed about how he sees the world. This means he was a character set against the main character, naruto's ideals. after that he pretty much sees many things the same as naruto so he isn't really against him anymore.
His murder was presumed to happen some time before the Chuunin selection process started, so Orochimaru could take his place and begin his plans to use the Hidden Village of the Sand to help destroy Konoha. The actual killing though was not shown until episode 127, as part of Kimimaro's back story.