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No you can't. The main reason is that there is no such thing as a "Blackberry Rio". The Rio is a inexpensive phone by Orange that just happens to look like a Blackberry. Although it looks similar, it lacks most of the features and is not compatible with Blackberry's software or applications.
There are no apps for Blackberry
almost all modern blackberry smartphones nowadays have BBM, so it does have it, and if it doesn't come with the phone, you can download it from BlackBerry App World or from the BlackBerry official site.
yes
BBM The acronym for Blackberry messenger is BBM. Blackberry's basic acronym is BB, although it is not used as commonly anymore now that Blackberry is on the decline.