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It depends on what you mean by bigger, but the answer to the question you're probably asking is yes. A .45 caliber bullet is .45 of an inch in diameter. A .44 caliber is .44 of an inch, so it's slightly smaller in diameter. However, .44 caliber bullets are many times longer and heavier. A common weight for .45s is 200 or 220 grain, and for .44s it's usually 240 grains.
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