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There is an App Store app on the iPod Touch that is used to download apps.
No, you cannot. iPod touch apps will only work with an iPod Touch or iPhone - no other touch screen mp3 player.
Add a background image to the iPod Touch via the Photos tab while the iPod is connected to iTunes. You can then select the image in the iPod's settings and set as wallpaper. (See links below)
You cannot make your apps transparent. Yes you can |:/
Apps can be removed at any time, but all apps that are on the iPod Touch will remain there unless you delete them.