Yes, if the sex is unprotected sex, by which we mean that contraceptives such as condoms or the pill etc are not used. If it is unprotected sex then a woman can get pregnant from the very first time she has sex.
If protection has been used properly in all cases of intercourse then the chances of pregnancy are highly unlikely, although there can be exceptions. For example condoms are 98% effective so for every 100 women that use them there is a chance 2 will become pregnant.
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