Slowpoke can be found in many various places, for it is exclusive to Pokemon LeafGreen version. It can be found at Routes 4, 10, 11, 12, 13, 14, 19, 20, 21, 24, and 25. It can also be found in Fuchsia City, Vermillion City, Viridian City, the Safari Zone in Fuchsia City, and all of the Sevii Islands.
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after obtaining the national dex go to route 205 north and use your poke radar in the grass
to catch Pokemon you have to obtain raikou palls
..you cant but if your game version is leafgreen,, you need to have a firered and link it with leafgreen using a link cable and trade the Pokemon in a Pokemon center
Some slowpoke or slowbro hold it in slowpoke well, or a guy gives it to you near where u catch the slowpoke. I know that's for HG SS, but not so sure with GSC. Nife ///R/ XXXXXXXXX
After you get the national dex go to Wayard cave and then insert Leaf green.
You can catch one in route 209 and route 214 if you have Pokemon leafgreen inserted in the gba slot of your DS.