Depends on whether she wants to bind, or be bound. One way to tell is if she likes being pinned down sometimes, and even more so if she's into 'rough' sex. Or you could just tell her you would like to try being tied up. Sex is like dancing: one person leads and the other follows. It may take a while to work out the steps!
If it seems like she's into it but you haven't really had experience with it, best to start out with something non-intimidating, like silk scarves or neckties.
Three rules: 1. Nothing around the neck until you really know what you're doing. 2. Never leave a person alone when they're tied up! 3. "No" still means "No."
Good luck and happy bondage! :)
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