bleach ost ceremony commences
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the episode is 110 when Ichigo encounters Shinji Hirako who tells Ichigo that he knows of Ichigo's problems and continues on to tell him that the hollow with in will take hold of his body until he is nothing more than a lowly hollow and sooner or later Ichigo realizes its true and joins the Vizards (its actually Visords) for training i recommend you start at episode 110. but if you just want to cut to the chase he joins up for training on episode 122 and starts to fight with his inner hollow on episode 123
Episode 110 - Reopening of the Substitute Business! The Terrifying Transfer Student
nope.. he's currently back as one of the captain of Gotei 13
The episode that Ryoma fights for the grip tape with Shinji is episode 22 titled, Kaoru no Sainan (Kaoru's Troubles)
As of the newest chapter, he is currently fighting Hollow Ichigo and Zangetsu in one form, so we'll have to keep checking :) Yes he did mange to at the end because Ichigo was able to over come hollow Ichigo and is now training to stay hollowfied his limit is 12 seconds at the moment and now zangetsu is back instead of Hollow Ichigo . You will find out that Zangetsu and Hollow Ichigo are the same people just in differnt body when u see hollow means he is control when you see zangetsu means he is in control