the episode is 110 when Ichigo encounters Shinji Hirako who tells Ichigo that he knows of Ichigo's problems and continues on to tell him that the hollow with in will take hold of his body until he is nothing more than a lowly hollow and sooner or later Ichigo realizes its true and joins the Vizards (its actually Visords) for training i recommend you start at episode 110. but if you just want to cut to the chase he joins up for training on episode 122 and starts to fight with his inner hollow on episode 123
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The answer is unknown. The author is still working on the manga's. In the anime though, they show Oriou (Ichigo's Friend) train.
They are turned into Hollows by Sosuke Aizen, and then saved by Kisuke Urahara.
Because at first Gangu had a brother named Kain.His brother was a Soul Reaper and was being murdered by another Soul Reaper in the Soul Society. Ichigo was a SoulReaper,he insulted Ichigo in bleach.
235 I believe
bleach ost ceremony commences