Hitsugaya, Renji, Matsumoto, Ikkaku and Yumichika came to Ichigo's school at the end of episode 114.
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As of 4/5/2010, there has not been a final battle between Ichigo and Ulquiorra in the animated series of Bleach -- at least, not in an episode released by Dattebayo. The last complete fight between the two (where one of them is defeated) is featured in episode 161 through 162. The next time they meet is in episode 216, then again in 226 before filler episodes begin. In the immediate future, it appears that Ichigo and Ulquiorra will meet once more in episode 266. In the manga, their final battle starts toward the end of chapter 339, "The Deathbringer Numbers," and finishes at the beginning of chapter 354, "Heart."
Toshiro met Hiyori on Bleach 280. It was really funny. SPOILER: Their's this one part where Toshiro asked Lisa and Hiyori if they could leave Aizen to him, because well Toshiro really hates Aizen, but Hiyori said no and........ well you guys have to see that. Man, that was funny, I kept laughing, so that's why i kinda know the answer to this quetion.
Senna (茜雫, Senna) is a character from the movie Bleach: Memories of Nobody. She is a young Shinigami that Ichigo Kurosaki and Rukia Kuchiki meet in the Human World. She is also the main female protagonist of the movie.[1]
They meet in episode 1
You will find the beginning of the fight with Tensa Zangetsu in episode 302 and guess you could follow the to be continued form there. Hope my answer was helpful. But does anyone know where Grimmjow fights Ichigo in his released form.