Nouns
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There are plenty of words that end with "tion", but none that start with K unfortunately!
There are no words in the English language that start with those letters, however there are thousands that end with 'tion'.
keratinisation
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Redemption, seduction, prevention, inspection, circumspection, introduction, station, ration, elation, inhalation, exhalation, notion, friction, abortion, nation, motion, solution, bastion, exemption, apparition.