There are plenty of words that end with "tion", but none that start with K unfortunately!
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Abnormal, approval and atypical are 8 letter words. They begin with the letter a and end with the letter l.
Mob and minicab are words that begin with the letter m and end with b.
Several four letter words begin with the letter q. However, there are no four letter words that begin with the letter q and end with the letter o.
Unscrew and undertow begin with the letter u. They end with letter w.
Nouns