Ash's Cyndaquil evolved into Quilava in An Old Family Blend!, the 182nd episode of Pokémon Diamond and Pearl and the 648th episode overall. Quilava has yet to evolve into Typhlosion, however.
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cyndaquil evolves at level 13
Cyndaquil evolves into Quilava at level 14, and then to Typhlosion at level 36.
It never does. It's been a Cyndaquil for the entire series.
14
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