theres no episode for that because wont marry misty
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not sure
episode 39.5
I guess Ash will marry Misty, because how I know is I heard Misty's best friends are her togepi and Ash. Even in Misty's Song Ash and Misty sounded romantic. Besides Misty is one of my favorite Pokemon trainers.
No.
misty does like ash but no one in Pokemon