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The Pikachu you start with in Pokémon Yellow will not evolve because the Pikachu in question is based on the Pikachu that belongs to Ash Ketchum of the Pokémon TV anime. Ash's Pikachu won't evolve because he likes himself just the way he is and prefers to stay that way rather than chage.

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Q: Why doesnt pikachu evolve in Pokemon Yellow?
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