The first time they duel was in the four-way duel in Alcatraz tower. Due to Joey, Marik was the first to lose all his life points, but this duel was only to decide the opponents for the semi-finals.
When Yugi and Marik duel for real, in the Battle City finals, Yugi is the winner.
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The duel between Yugi and Marik is from episode 138 to 142 of the original duel monster series.
The Pharaoh wins in Duel Monsters episode 163. However Yugi wins in episode 224, the last episode of the Duel Monster series.
Alot of times. (:
Yes. 3000/5000 (depending on which version you watch!) years before the storyline of the Duel Monster series, the Pharaoh Atem defeated, but was unable to destroy, an evil entity called Zorc, sealing it into the Millenium Ring at the cost of his own life - he sealed his own soul into the Millenium Puzzle. At the very end of the Duel Monsters series, he duels Yugi. If he wins, then he'll be forced to remain in the world for another 3000 years. However if Yugi wins, the two can be split, and the Pharaoh can pass on to the afterlife. Yugi does win, and the Pharaoh's soul passes on.
yes yugi wins at battle kingdom and battle city