Volkner,Gym number 8.He has ELECTRIC type pokemon.The clever Volkner must know that Octillery isn't an Electric type,it's a water type.
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There are two swimmers ready for a double battle in route 223 , battle them and one will have an octillery . ;):)
Octillery
you can find the trainer with the misdreavus in platinum in hearthome city i believe
The trainer in victory road
There are two trainers ready for a double battle in route 223 [you need to have surf] one of them has an octillery ! Their names are Swimer Colton and swimmer Paige