on mega video episode 230
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they fuse in episode 253 of dbz thanks for the question
u can't fuse there is no majin buu saga or janemba saga it only goes on untill goku, vegeta, teen gohan and piccolo vs broly
In episode 153 (episode 168 in the original, non-dubbed episode) of Dragonball Z, Gohan and Goku emerge from the hyperbolic time chamber. After Goku and Gohan leave the time chamber Piccolo, Vegeta and Trunks then use the chamber for themselves.
Be more Specified DBZ Babidi made him a Majin as SSJ2 and tries to control him but it did not work because he wanted to battle Goku... OR DBGT Bebi controlled Vegeta and tries to take over the earth because of him wanted revenge on when Vegeta was bad he destroyed their planet.
if I'm not mistaken its episode 280 in the uncut version and the episode is called "Vegeta's Respect"