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Chimchar is not obtainable in Pokemon FireRed or LeafGreen. The game it is in (Such as; Pokemon Pearl, Diamond, and Platinum.) is unable to connect to FireRed, unless migrating Pokemon from it, but Pokemon cannot be transferred into the Gameboy Advance games.
You get a Chimchar if you want it as your 1st Pokemon
You cannot catch Chimchar in the wild in Pokemon Pearl. You can only get chimchar either at the beginning of the game, or breeding a chimcharm, infernape, or monferno. Otherwise, you need an Action Replay to catch a chimchar in the wild.
To get Pokemon firered on PC download a vba and Pokemon firered ROM
Go to the desert and walk around until you see a chimchar