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You can find different colored shards on certain routes on the Pokewalker accessory.
You can get them using the dowsing MCHN on the Pokewalker or you have a chance of getting them by using Rock Smash on any rock (You can get red, blue, green and yellow shards this way as well as heart scales, revives, max ethers, and fossils).
Underwater
Red Shard Blue Shard Yellow Shard Green Shard Violet City and Fuchsia City
Theres a treasure hunters house between lilycove and mossdeep. You get the water stone(evolves stayu) if you give him the blue shard the hunters house is just West of Mossdeep. On a mini island. You can trade: green shard for leaf stone, blue shard for water stone, red shard for frie stone and that's all i know.