Go to the national park not during a contest. In the bottom left is a lady. Talk to her and she gives you the quickclaw
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The Quick claw is located in the National Park in Pokemon Heartgold and Soulsilver.
You can get the quick claw in the safari zone.
a quick claw is what you give a Pokemon to increase itsspeed
Quick Claw increases the possiblity of your Pokemon attacking first in battle.
There is no item that ALWAYS makes your Pokemon go first, but quick claw does let them go first more often.