In Pokémon Diamond, the only way to acquire the Electirizer item that evovles Electabuzz is to insert the Pokémon FireRed Game Pak game into the bottom slot of your Nintendo DS or Nintendo DS Lite and then you have to find wild Elekid which will be in the grass routes of the Valley Windworks as well as in the south valley section of Route 204. Wild Elekid will be holding the Electirizer item.
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You first have to upgrade to the national pokedex then go and catch elekid to get the Electrizer
If you have an electrizer you can use it to evolve electabuzz by letting electabuzz hold it and then trade it.
The electrizer on Pokemon Diamond is used by Electabuzz to evolve into Electivire. To get the electrizer in Pokemon Diamond you must have inserted Pokemon Firered in the game boy slot.
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To get the Electrizer in Pokemon Diamond or Pearl, you must have Pokemon FireRed inserted in Game Boy slot. FireRed allows you to catch an Elekid at the Fuego Ironworks, which have a 50% chance to hold an Electrizer for Diamond, 5% for Pearl. For Pokemon Platinum, go to Route 205 and go to the bridge. Use Surf at the right side of the bridge, and follow the river until you see the second turbine. Land next to the second turbine, and there should be a pokeball there. Obtain it and it should say that you just got the Electrizer.