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To get the Electrizer in Pokemon Diamond or Pearl, you must have Pokemon FireRed inserted in Game Boy slot. FireRed allows you to catch an Elekid at the Fuego Ironworks, which have a 50% chance to hold an Electrizer for Diamond, 5% for Pearl. For Pokemon Platinum, go to Route 205 and go to the bridge. Use Surf at the right side of the bridge, and follow the river until you see the second turbine. Land next to the second turbine, and there should be a pokeball there. Obtain it and it should say that you just got the Electrizer.

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Q: How do you get an Electrizer in Pokemon Diamond Version?
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