You can find a Sun Stone in Raimon/Nimbasa City (The 4th Gym City) The Sun Stone can be obtained from a person in the apartment left of the Battle Subway on the 2nd floor.
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Evolve a Krokorock with a Sun Stone
Cottonee evolves by sun stone. If you have a sun stone you can evolve it at any time.
Pokemon requiring a stone to evolve:Eevee - Thunder stone, Jolteon (you can't find this Pokemon in Ruby) Eevee- fire stone, Flareon (you can't find this Pokemon in Ruby)Eevee- water stone, Vaporeon (you can't find this Pokemon in Ruby)Sunkern- sun stone, Sunflora (you can't find this Pokemon in Ruby)Jigglypuff- moon stone, WigglytuffSkitty - moon stone, DelcattyNidorino- moon stone, Nidoking (you can't find this Pokemon in Ruby)Nidorina- moon stone, Nidoqueen (you can't find this Pokemon in Ruby)Growlithe- fire stone, Arcanine (you can't find this Pokemon in Ruby)Gloom- sun stone, BellosumGloom- leaf stone, VileplumeStaryu- water stone, StarmiePikachu- thunder stone, RaichuLombre- water stone, LudicoloNuzleaf- leaf stone, ShiftryVulpix- fire stone, NinetalesHappiny- oval stone Chansey
Petilil will evolve with a sun stone, pansage with a leaf stone, panpour with a water stone, and pansear will evolve with a fire stone.
Use a sun stone on a Gloom.