When you choose your starter, it has a 1/8 chance of being female. Therefore, female species of every starter are quite rare, but not impossible!
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Good/Answer 2:You can breed a Chimchar and hope its female, or do trading at GTS in Jubilife. :3Answer 1:you cant chimchars are only male
Pick Piplup or Chimchar and then trade for a piplup or chimchar
CHIMCHAR
You get a Chimchar if you want it as your 1st Pokemon