in map 6
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check in the pokedex
I'm not sure if you can catch Eevee in Pokemon pearl but you get it as a gift from Bebe in Hearthrome City after you get the national dex.
defeat all gyms,elite 4 and champion of that region to catch legendary pokemon
It cannot be caught in Pokemon white but can be transferred from a generation IV game.You aren't able to catch a wild Eevee in pokemon white or black, you have to trade it from a different pokemon game with Eevee as a catchable pokemon. Hope that helped :)
You can't catch Espion you must evolve it from an Eevee by using a moon stone on it to get an eevee go to Heathome city in the house next to it to get an eevee.