Near mossdeep ciry
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That can be found underwater near the hunter's house west of mossdeep city.
find one in the firey path or trade 1 red shard for one at the hunter's house
I think there are an Unlimited number, because if you manage to get a green shard from a wild pokemon, you can trade it with the shard hunter for a leaf stone. (He has an unlimited number of them, as long as you have a green shard to give him.)
you can find it on route 124 I've had a vulpix and to make it evolve i had find the red shard and i had to give it to hunter in mossdep city to get the fire stone
u gotta find a red shard & give it to Hunter to the left of mossdeep city. He lives on an island with one house on it.