theres a guy who will teach it to whenever u want in route 34
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you go to Ilex forest and find a man in there and he will give you headbutt and teach it to you Pokemon and now you could headbutt a tree
Yes you can catch a hoot hoot in soul silver you can get one by going in the rock tunnel in kanto & catching a cubone that should know headbutt. then walk up to a tree in kanto and use cubone's headbutt and that's how u get a hoot hoot.
When facing the tree, go to your Pokemon and select the one that has the move HEadbutt. Then use it.
pineco are insanly hard to get if you just headbutt random trees go to serebii.net category Pokemon soulsilver and hit headbutt it tells you what tree gets you what Pokemon or use honey on a tree 40 % chance youll get a pineco with honey
headbutt tree