That would depend on what game you are playing.
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near the exit at the top
In Pokemon Yellow, Moltres can be found on Victory Road. _____ Going towards Indigo Plateau or the Pokemon League, near the exit of Victory Road (you have to have all the badges to get there), you will find Moltres.
You go to victory road, go to pokemon league, then go inside victory road from its exit, turn right go through the door on the left and terrakian will be there
1st you have to get through victory road 2nd you have to beat the elite four 3rd you go back into victory road and go into the cave to the right Keep goin through until you exit the caves. =)
you have to go through giant chasm until you see a cave exit on the western side. then go through route 23 and you will arrive at the badge check gate. victory road is at the end of that gate.