You can't in Fire Red or Leaf Green. You would have to trade the item over from Emerald or Ruby and Sapphire.
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In Pokemon firered you can't, but in Pokemon leafgreen you can get it then trade it to Pokemon firered.
battle tower 48 bp
To get Pokemon firered on PC download a vba and Pokemon firered ROM
Yes there are shiny Pokemon in firered
The Choice Band can be bought from a vendor on Pokemon Platinum in the Battle Frontier for 48 BP. To get BP simply take part in the various special battle arenas within the Frontier.