in castellia city, as you walk around go to the way back in the city but dont go through allys until the last one, it will be on the 1st door on your right. it looks like a fancy art museum
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You cannot re-battle the Gym Leaders in Pokémon Black and White.
The Unova gym leaders are; !st gym: Cilen, Chili, and Cress 2nd gym: Lenova 3rd gym: Burgh 4th gym: Elesa 5th gym: Clay 6th gym: Skyla 7th gym: Brycen 8th gym: Drayden(pokemon black) and Iris(pokemon white)
You cannot rebattle Gym Leader in Pokemon White.
Because black and white is a reboot; in the original series ash traveled with brock and misty, 2 gym leaders. So in Black and white series ash travels with cilan and iris, also gym leaders.
The Nimbasa Gym is right of were the old one was (in black / white), past the Ferris wheel, look for the pokeball symbol on the building