You can't capture teddiursa in leafgreen but in emerald you can in a special johto area of the safari zone after beating the Pokemon league you can enter this area. Also trade the purified teddiursa from Pokemon xd gale of darkness to leafgreen or get the purified ursaring from Pokemon colosseum then breed it in leafgreen to get teddiursa.
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Yes you can catch it before the elite four, you can get larvitar after the zafari zone opens in heart gold soul silver which opens after you deliver the secret potion to jasmine of Olivine city. Larvitar can be found in the mountain region of the zafari zone but is rare.
AnswerThe Pokemon available in the Safari Zone are much like those available in Pokemon Red and Blue. The Pokemon which can be obtained in FireRed are as follows: On landNidoran (Male)NidorinoNidorinaExeggcuteParasParasectRhyhornDoduoKangaskhanVenonatVenomothTaurosScytherChanseyWhile Surfing or fishingMagikarpPoliwagGoldeenSeakingPsyduckKrabbyDratiniDragonairOther Pokemon normally captured in the Safari Zone can only be obtained in Pokemon LeafGreen.
The safari zone.
Psyduck is in firered not leafgreen you can find it using a good or super rod in the safari zone.
The Safari zone is in fuchia citythe same place as fire red, Fuchsia City.the safari zone is in Fuschsia City.