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Qwilfish is caught in firered at five island using a super rod in the water its a little rare so it may take time also a shadow qwilfish is available in Pokemon colosseum.
you can't catch qwilfish in emerald. the only gba Pokemon game that I know has qwilfish is fire red. However to the answer stated above you can catch Qwilfish in Pokemon Colloseum, purify it, and then trade it to Emerald via. a GNC/GBA connector cable.
The following list of pokemon are catchable or obtainable in Pokemon Firered: Ekans Arbok Oddish Gloom Vileplume Psyduck Golduck Growlithe Arcanine Shellder Cloyster Scyther Electabuzz Bellossom Wooper Quagsire Murkrow Qwilfish Scizor Delibird Skarmory Elekid Deoxys (Attack Forme)* *Deoxys is an Event pokemon that can only be obtained with cheat codes and it has three forms, Attack, Defense, and Speed. The attack forme is exclusive to Firered.
In Pokemon firered you can't, but in Pokemon leafgreen you can get it then trade it to Pokemon firered.
Quilava, Quagsire, Qwilfish, and Quilladin.