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Well, I'm afraid you cannot get Mimic in Pearl; Mimic is not a TM. But some Pokémon can learn it, if that's what you mean. In which case, the following can learn Mimic:

  • Jigglypuff at Lv. 41
  • Mr. Mime at Lv. 18
  • Sudowoodo at Lv. 17
  • Bonsly at Lv. 17
  • Mime Jr. at Lv. 18
  • Chatot at Lv. 29
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15y ago

What else can I help you with?