National Park bug catching contest on the Thursday on between 1 - 3 pm and levels 26 - 30 in the far back patch towards the fence opening. It's quite hard to find.
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You can find a dustox in eterna forest and there is also a trainer with dustox there too.
You are able to get Dustox by evolving Cascoon. Wurmple-Silcoon-Beautifly Wurmple-Cascoon-Dustox
I think that Team Galactic's members usually have Dustox.
Dustox can be found in Eterna Forest. it can also be found by battling these two bug catchers
There is no best Pokemon on Pokemon HeartGold.