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Give a Pokemon in Pokemon Emerald, Sapphire, or Ruby a luxury ball to hold and trade to Fire Red. You can get extra luxury balls by winning a master rank contest after your Pokemon already has the ribbon. There is also one luxury ball in the abandoned ship, but you need dive. As far as I know, you cant get the luxery bal without tradeing with the other games I listed, or trade with someone who already has luxury balls. -BubbaJ
use a ultra/great ball
Quick balls don't exist in sapphire.
The sunken SHip, or the Quiz Lady, or the Pokemon Lottery.
It is a special pokeball that has a catch rate between a pokeball's and a great ball's. If you catch a pokemon with a luxury ball, the pokemon will grow friendly to you much faster than normal. This is good because there are several pokemon that will only evolve if they like you a TON. Some of these are Munchlax, Togepi and Golbat