To get the leaf stone in Pokémon Ruby you need to first go to the area of the Weather Institute. Next surf north to the waterfall and you will find the stone.
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Nuzleaf will evolve into Shiftry and the leaf stone will turn Gloom into Vileplume.
Pokemon requiring a stone to evolve:Eevee - Thunder stone, Jolteon (you can't find this Pokemon in Ruby) Eevee- fire stone, Flareon (you can't find this Pokemon in Ruby)Eevee- water stone, Vaporeon (you can't find this Pokemon in Ruby)Sunkern- sun stone, Sunflora (you can't find this Pokemon in Ruby)Jigglypuff- moon stone, WigglytuffSkitty - moon stone, DelcattyNidorino- moon stone, Nidoking (you can't find this Pokemon in Ruby)Nidorina- moon stone, Nidoqueen (you can't find this Pokemon in Ruby)Growlithe- fire stone, Arcanine (you can't find this Pokemon in Ruby)Gloom- sun stone, BellosumGloom- leaf stone, VileplumeStaryu- water stone, StarmiePikachu- thunder stone, RaichuLombre- water stone, LudicoloNuzleaf- leaf stone, ShiftryVulpix- fire stone, NinetalesHappiny- oval stone Chansey
Go to liyovile city and then go to the general store and buy it
around level 43 :)
To get the Leaf Stone you have to go to the river on 119 near the Weather Institute. Surf down and you will find a pokeball. Pick it up and it will be a leafstone.