Tm 65 shadow claw is only available in Pokemon diamond/pearl ad patinum
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After you beat fantina at the gym in hearthome city she will give you the TM shadow claw.
yoursadasking about pokemon
you can get shadow claw on the goldenrod lottery on mondays as first price. and at route 42. hope this helps!
You can give it to the Scientist in the Devon Corporation building in Rustboro.