To find heart scales on Pokemon diamond/pearl you need the explorer kit to go underground. once you are underground look for cracks inthe wall, and eventully you will find a heart scale in the cracks.
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underground
on Pokemon diamond and pearl you will need the explore kit to go underground then after mining the walls for loot there is a chance you may find a heart scale also fosils and evoloution stones
Heart Scales can be purchased in the Pokeathlon shop for 1000P
You can find the Heart Scale under ground by using the Explorer Kit.
Heart scales can typically be found underground by using the Explorer Kit.