That item doesn't exist in leafgreen.
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Piplup does not exist in Pokemon LeafGreen or FireRed.
In Pokemon Diamond and Pearl, a Protector can be found on Route 228. In Pokemon Platinum, a Protector can be found on Iron Island.
You cannot catch houndour in Pokemon leafgreen either get one from Pokemon emerald or Pokemon colosseum.
after you beat the Pokemon league u go 2 the island in the northeast and u will find a desert.then you might find a protector there.
Nowhere.