nowhere,but you can get one from professor rowan
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You cannot catch Chimchar in the wild in Pokemon Pearl. You can only get chimchar either at the beginning of the game, or breeding a chimcharm, infernape, or monferno. Otherwise, you need an Action Replay to catch a chimchar in the wild.
neither of them is better, they are both the same, but in diamond, you catch dialga, and in pearl, you catch palkia, and you can catch different Pokemon in each game for example: you can catch this Pokemon in diamond, but not pearl but: you can catch this different Pokemon in pearl, but not diamond
You can use Feint (if you have diamond/pearl/platinum, monferno learns it).
On route 215 there are two trainers, Dennis and Maya. During the double battle, Dennis will send out a Monferno. Also if you started off with a Turtwig, your rival will have a Monferno in his party.
Lucas has a Monferno.