You can catch Electabuzz on Route 10, after you can go to Kanto. He is only found in the grass in front of the Power Plant. If you don't know how to reach that part, you have to Surf down the river that starts in Route 9.
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Your Poke-walker in Suburban Area, or breed an Electabuzz (catch in Kanto's power plant)
To catch an electabuzz, you must be in the Forest Area. View the related link below for more information.
You can catch Electabuzz. It is at the Power Plant, but it is rare.
You can only catch them in Pokemon fire red.
You cant actually CATCH electabuzz in Pokemon sapphire/emerald/ruby, but u can trade electabuzz from fire red, and Pokemon XD. happy to help