you have to trade
You have to trade from ruby sapphire or emerald or trade with a friend
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Rayquaza
You can only get Rayquaza in Pokemon Ruby, Sapphire, and Emerald. If you want to get a Rayquaza in Pokemon Leafgreen or Firered, you will have to get a second Game Boy Advance or SP with a link cable to trade Rayquaza into your firered or leafgreen.
You can not catch it in leafgreen,but in firered you can.
How do you catch rayquaza in Pokemon black and white
Nowhere no hoenn Pokemon can be captured in leafgreen.