The goldenrod city underground
there are two haircut brothers that appear on different days! have fun ;)
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Go to the underground entrance near Bill's house in Goldenrod City. The haircut brothers appear everyday, besides Mondays, in real time.
You can't give your Pokémon a haircut in Sapphire.
you cant get a haircut in pokemon black and white only x and y so on
There are no groomers in Pokemon Pearl, but you can take your Pokemon to get a massage by a lady in Veilstone City. This boosts their Happiness like it would with a haircut.
Haircut Brother #1 is in Goldenrod Underground on Tuesday, Thursday and Saturday. He's the more expensive of the two (at 500) and is more reliable and increases happiness more. Haircut Brother #2 is in Goldenrod Underground on Wednesday, Friday and Sunday. He's the cheaper of the two (at 300) but is less satisfactory.