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Go to pecifilog (the town closest to sky pillar) and in the pokecenter there is a person in one of the corners (I think the bottom left) and they will tech on of your Pokemon expolsion once and only once. You can also get some Pokemon that learn explosion/self-destruct via leveling up or move tutor, hope I helped
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Earn +20 ptsQ: Where can you get the move explosion on Pokemon emerald?
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