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On Route 120 you have to use Theif on Bug Manic Brandon's Pokemon.

Information on Theif...

Poochyena (Lv.45), Mighyena (Lv.52), Lombre (Lv.37), and Kecleon (Lv.-) learn it by leveling up. As for Kecleon, I recommend making it remember Theif.

I do not have the info for getting the TM46 Theif.

Credit to Serebii.net (This website is super awesome! It contains loads of information on Pokemon!)

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