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Magmar is unavailable on Pokémon Emerald. He can be traded in from other games, or you could cheat...
Magmar doesn't evolve in Pokemon Red, Blue, Yellow, Green, Silver, Gold, Crystal, Ruby, Sapphire, Emerald, FireRed, or GreenLeaf. It can only evolve in the newer Pokemon games.
give your magmar a magmirizer and trade with it to get the evolve form of magmar.
The only way to obtain Magmar in Pokemon FireRed is to trade it from LeafGreen.
None magmar is only obtainible in leafgreen and Pokemon xd gale of darkness.